H2O-CH4-H2-CO2-CO-O2在高温、高压和高密度条件下的状态方程     

胡家文 《地球化学》2002,31(4):389-394

为了计算高温，高压和高密度流体的热力学性质，提出了一个具有19个参数的维里型状态方程，其中参数与温度间的函数关系采用由Sutherland位能函数导出的维里系数近似式。除临界点附近以外，在已报道的pVT数据所覆盖的大部分超临界区域内，该方程均可适用。用该方程对H2O，CH4，H2，CO2，CO和O2等流体pVT关系的计算结果令人满意，其中pVT上限分别为：91-610GPa,1.6-11.0cm^3/mol,4000-5000K。计算体积的平均偏 小于0．8％，最大偏差小于5．4％。  相似文献   

离散裂隙渗流方法与裂隙化渗透介质建模   总被引：4，自引：1，他引：4  

王明玉  陈劲松等 《地球科学》2002,27(1):90-96

流体渗流模拟的连续介质方法通常适用于多孔地质体，并不一定适用于裂隙岩体，由于裂隙分布及其特征与孔隙差异较大。若流体渗流主要受裂隙的控制，对于一定尺寸的裂隙岩体，多孔介质假设则较难刻划裂隙岩体的渗流特征。离散裂隙渗流方法不但可直接用于模拟裂隙岩体非均质性和各向异性等渗流特征，而且可用其确定所研究的裂隙岩体典型单元体及其水力传导（渗透）张量大小。主要讨论了以下问题：（1）饱和裂隙介质中一般的离散流体渗流模拟；（2）裂隙岩体中的REV（典型单元体）及其水力传导（渗透）张量的确定；（3）利用离散裂隙网络流体渗流模型研究裂隙方向几何参数对水力传导系数和REV的影响；（4）在二维和三维离散裂隙流体渗流模型中对区域大裂隙和局部小裂隙的处理方法。调查结果显示离散裂隙流体渗流数学模型可用来评价不同尺度上的裂隙岩体的水力特征，以及裂隙方向对裂隙化岩体的水力特征有着不可忽视的影响。同时，局部小裂隙、区域大裂隙应当区别对待，以便据其所起的作用及水力特征，建立裂隙化岩体相应的流体渗流模型。  相似文献   

山东金青顶金矿床和七宝山金矿床的流体包裹体REE组成   总被引：6，自引：0，他引：6  

陈绪松  徐九华  刘建明  谢玉玲  朱和平  李永兵 《矿床地质》2002,21(4):387-392

文章运用电感耦合等离子体质谱（ICP-MS）方法，研究了金青顶金矿床和七宝山金矿床的脉石英中流体包裹体REE组成特征，结果表明流体包裹体的REE均为LREE富集型，并显示Eu正异常。成矿流体REE配分模式和REE参数特征表明它们具有相当的来源。与金矿有关的成矿母岩，即昆嵛山花岗岩和七宝山次火山岩的REE特征也极为相似，反映成矿流体的REE组成都有从成岩向成矿过程演化继承的关系。矿床流体包裹体REE组成的相似特征及矿床碳氧同位素等特点表明，金青顶金矿床和七宝山金矿床是华北东部中生代同一构造热事件的产物。  相似文献   

华北克拉通北部内、外缘中生代流体成矿作用研究--以大井、蔡家营典型矿床为例     

曲丽莉  王莉娟  王玉往 《矿产与地质》2002,16(4):193-198

华北克拉通北部内、外缘中生代形成的有色金属矿种繁多 ,以外缘富 Sn、内缘富 Mo,Cu、Pb、 Zn遍布内、外缘为主要特色。通过内、外缘典型矿床的研究和综合对比 ,认为外缘的富 Sn是与富 Sn的基底有关 ,内缘的富 Mo是与结晶基底地层和岩浆热液关系密切。而内、外缘 Cu、 Pb、 Zn的成矿与中生代构造转折 ,造成大规模陆相火山活动和成矿流体的卸载密切相关  相似文献   

川滇密西西比河谷型铅锌矿床成矿流体来源研究:流体Na-Cl-Br体系的证据   总被引：11，自引：1，他引：11  

李泽琴  王奖臻  倪师军  李朝阳  胡晓强  李桃叶 《矿物岩石》2002,22(4):38-41

应用流体包裹体滤液分析方法，测定了川滇7个MVT铅锌矿床成矿流体的Na,Cl,Br含量，结果表明成矿流体的x(Na/Br)和x(Cl/Br)的平均值分别为185和73，并与高度蒸发浓缩的残留海水的x(Na/Br)和x(Cl/Br)相近。成矿流体的Na,Cl含量呈正相关，在lgNa-lgCl图解中呈线性分布。根据这些事实以及矿床地质特征，认为原始成矿卤水起源于蒸发浓缩的残留海水，原始含矿卤水与富含有机质的大气降水混合导致矿质沉淀而成矿。  相似文献   

Origin of Gold—Bearing Fluid and Its Initiative Localization Mechanism in Xiadian Gold Deposit,Shandong Province     

邓军  王庆飞  孙忠实 《中国地球化学学报》2002,21(3):282-288

The composition of quartz inclusions and trace elements in ore indicate that gold-bearing fluid in the Xiadian gold deposit,Shandong Province,stemmed from both mantle and magma,belonging to a composite origin.Based on theoretical analysis and high temperature and high pressure experimental studies,gold-bearing fluid initiative localization mechanism and the forming environment of ore-host rocks are discussed in the present paper.The composite fluid extracted gold from rocks because of its expanding and injecting forces and injecting forces and flew through ore-conducive structures,leading to the breakup of rocks.The generation of ore-host faults and the precipitation of gold-bearing fluid occurred almost simultaneously.This study provides fur-ther information about the relationships between gold ore veins and basic-ultrabasic vein rocks and intermediate vein rocks,the spatial distribution of gold ore veins and the rules governing the migration of ore fluids.  相似文献   

Constraints on the application of carbon isotope thermometry in high- to ultrahigh-temperature metamorphic terranes   总被引：7，自引：0，他引：7  

M. Satish-Kumar  H. Wada  M. Santosh 《Journal of Metamorphic Geology》2002,20(3):335-350

Nine marble horizons from the granulite facies terrane of southern India were examined in detail for stable carbon and oxygen isotopes in calcite and carbon isotopes in graphite. The marbles in Trivandrum Block show coupled lowering of δ¹³C and δ¹⁸O values in calcite and heterogeneous single crystal δ¹³C values (? 1 to ? 10‰) for graphite indicating varying carbon isotope fractionation between calcite and graphite, despite the granulite facies regional metamorphic conditions. The stable isotope patterns suggest alteration of δ¹³C and δ¹⁸O values in marbles by infiltration of low δ¹³C–δ¹⁸O‐bearing fluids, the extent of alteration being a direct function of the fluid‐rock ratio. The carbon isotope zonation preserved in graphite suggests that the graphite crystals precipitated/recrystallized in the presence of an externally derived CO₂‐rich fluid, and that the infiltration had occurred under high temperature and low f_O2 conditions during metamorphism. The onset of graphite precipitation resulted in a depletion of the carbon isotope values of the remaining fluid+calcite carbon reservoir, following a Rayleigh‐type distillation process within fluid‐rich pockets/pathways in marbles resulting in the observed zonation. The results suggest that calcite–graphite thermometry cannot be applied in marbles that are affected by external carbonic fluid infiltration. However, marble horizons in the Madurai Block, where the effect of fluid infiltration is not detected, record clear imprints of ultrahigh temperature metamorphism (800–1000 °C), with fractionations reaching <2‰. Zonation studies on graphite show a nominal rimward lowering δ¹³C on the order of 1 to 2‰. The zonation carries the imprint of fluid deficient/absent UHT metamorphism. Commonly, calculated core temperatures are > 1000 °C and would be consistent with UHT metamorphism.  相似文献   

Origin of fine-scale sheeted granites by incremental injection of magma into active shear zones: examples from the Pilbara Craton, NW Australia   总被引：1，自引：0，他引：1  

M. J. Pawley  W. J. Collins  M. J. Van Kranendonk 《Lithos》2002,61(3-4):127-139

In the Archaean Pilbara Craton of Western Australia, three zones of heterogeneous centimetre- to metre-scale sheeted granites are interpreted to represent high-level, syn-magmatic shear zones. Evidence for the syn-magmatic nature of the shear zones include imbricated and asymmetrically rotated metre-scale orthogneiss xenoliths that are enveloped by leucogranite sheets that show no significant internal strain. At another locality, granite sheets have a strong shape-preferred alignment of K-feldspar, suggesting magmatic flow, while the asymmetric recrystallisation of the grain boundaries indicates that non-coaxial deformation continued acting upon the sheets under sub-solidus conditions. Elsewhere, randomly oriented centimetre-wide leucogranite dykes are realigned at a shear zone boundary to form semi-continuous, layer-parallel sheets within a magma-dominated, dextral shear zone.

It is proposed that the granite sheets formed by the incremental injection of magmas into active shear zones. Magma was sheared during laminar flow to produce the sheets that are aligned sub-parallel to the shear zone boundary. Individual sheets are fed by individual dykes, with up to 1000s of discrete injections in an individual shear zone. The sheets often lack microstructural evidence for magmatic flow, either because the crystal content of the magma was too low to record internal strain, or because of later recrystallisation.  相似文献   

REE Geochemistry of the Lead—Zinc Ores from the Jinding Lead—Zinc Deposit,Lanping,Yunnan   总被引：3，自引：1，他引：3  

牟传龙  余谦  张立生 《中国地球化学学报》2002,21(1):57-64

Nineteen volcanic and magmatic rock samples were collectecd from the Jinding leadzinc deposit and its surrounding areas in Yunnan.The ICP and AES analyses,feferred to the previous results,show that the metal minerals and altered rocks in the Jinding lead-zinc deposit display a decreasing trend of ∑REE from the early to late stages of mineralization,and similarities in REE distribution patterns,indicating that the ore fluids are characterized by high LREE enrichment,markedly negative δCe anomaly and slight δEu anomaly.These REE distribution paterns exhibit striking similarities to those of the Pliocene trachyte in the study area,both of which are similar in ∑REE,LREE/HREE ratio,δEu and δCe.The ore fluids besides the basin fluids in the deposit are also closely related to those associated with Pliocene trachyte magmas.  相似文献   

Caractérisation des paragenèses et des paléocirculations fluides dans l'indice d'or de Bleı̈da (Anti-Atlas,Maroc)Characterization of the paragenesis and the fluid palaeo-circulations in the gold showings of Bleida (Anti-Atlas,Morocco)     

Ahmed Barakat  Christian Marignac  Marie-Christine Boiron  Mohamed Bouabdelli 《Comptes Rendus Geoscience》2002,334(1):35-41

The gold showings at Bleida are hosted in Late Pan-African N50–80 °E quartz–hematite–chlorite 1 tension lenses that are related to the activity of major sinistral sub-east–west thrusts. Ores result from three superimposed stages of fluid migration. Gold occurs in microcracks offsetting the earlier minerals. Fluids evolved from COHN compositions with a saline component to boiling aqueous fluids. Pressure and temperature decreased from 50 MPa and 300 °C to less than 4 MPa and 150 °C. Thus, the gold showings at Bleida were formed in a typical geothermal (epithermal) setting, likely controlled by the Late Pan-African magmatism. To cite this article: A. Barakat et al., C. R. Geoscience 334 (2002) 35–41  相似文献